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Professor Lena F. Kourkoutis

Thursday, Sep 14, 2017 at 4:00 PM until 5:00 PM [.ics]
B11 Kimball

New frontiers in cryo-electron microscopy: From Probing Low Temperature Electronic Phases to Processes at Liquid/Solid Interfaces

Spectroscopic mapping by STEM/EELS has proven to be a powerful technique for determining the structure, chemistry and bonding of interfaces, reconstructions, and defects. So far, most efforts in the physical sciences have focused on room temperature measurements where atomic resolution mapping of composition and bonding has been demonstrated [1-3]. For many materials, including those that exhibit electronic and structural phase transitions below room temperature and systems that involve liquid/solid interfaces, STEM/EELS measurements at low temperature are required. Operating close to liquid nitrogen temperature gives access to a range of emergent electronic states in solid materials and allows us to study processes at liquid/solid interfaces immobilized by rapid freezing [4,5].

Here, we will discuss our approach to study two processes at the anode-electrolyte interface in lithium metal batteries (LMBs), uneven deposition of lithium metal leading to dendrite growth and the breakdown of electrolyte to form a “solidelectrolyte interphase” (SEI) layer, processes which result in capacity fade and safety hazards. By combining cryo- STEM/EELS with cryo-FIB lift out [5], we provide nanoscale compositional information about intact SEI layers in cycled LMBs and track local bonding states at interfaces, leading to new insights into SEI and dendrite formation.

We will further demonstrate cryo-STEM imaging at sub-Å resolution and atomic tracking with picometer precision in charge-ordered manganites. Using this technique, we measure transverse, displacive lattice modulations of the cations, distinct from existing manganite charge-order models and reveal temperature-dependent inhomogeneities in the stipe order such as shear deformations and topological defects, and the emergence of phase coherence well below Tc [4, 6]. Correlating the atomic level structure and electronic properties at cryogenic temperatures is an important step in realizing the goal of understanding and controlling emergent phenomena in these materials.

 

[1] K. Kimoto, T. Asaka, T. Nagai, M. Saito, Y. Matsui, K. Ishizuka, Nature 450 (2007) 702.

[2] D.A. Muller, L.F. Kourkoutis, M. Murfitt, J.H. Song, H.Y. Hwang, J. Silcox, N. Dellby, O.L. Krivanek,

Science 319 (2008) 1073.

[3] J.A. Mundy, Y. Hikita, T. Hidaka, T. Yajima, T. Higuchi, H.Y. Hwang, D.A. Muller, L.F. Kourkoutis,

Nat. Commmun. 5 (2014) 3464.

[4] I. El Baggari, B.H. Savitzky, A.S. Admasu, J. Kim, S.-W. Cheong, R. Hovden, L.F. Kourkoutis, arXiv:

1708.08871 (2017).

[5] M.J. Zachman, E. Asenath-Smith, L.A. Estroff, L.F. Kourkoutis, Microsc. Microanal. 22 (2016) 1338.

[6] B.H. Savitzky, I. El Baggari, A.S. Admasu, J. Kim, S.-W. Cheong, R. Hovden, L.F. Kourkoutis,

Lena F. Kourkoutis is an Assistant Professor of Applied and Engineering Physics and James C. and Rebecca Q. Morgan Sesquicentennial Faculty Fellow at Cornell University. Her electron microscopy group focuses on understanding and controlling nanostructured materials, from complex oxides to materials for energy storage to biomaterials. They use some of the most advanced electron microscopes to study these systems atom-by-atom and develop new cryogenic techniques to gain access to low temperature electronic states as well as to study processes at liquid/solid interfaces.

Kourkoutis received her undergraduate degree in Physics from the University of Rostock, Germany in 2003, and then moved to Ithaca where she was awarded a Ph.D. in 2009. As a Humboldt Research Fellow, she spent 2011-2012 in the Molecular Structural Biology Group at the Max Planck Institute of Biochemistry in Martinsried, Germany. She returned to Cornell University in 2012 and joined the Cornell Faculty in 2013. Kourkoutis is recipient of the 2013 Albert Crewe Award, a 2014 Packard Fellowship for Science and Engineering, a 2016 Presidential Early Career Award for Scientists and Engineers, presented by President Barack Obama, and a 2017 NSF CAREER award. She is also a Kavli Fellow of the National Academy of Sciences.

 

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